WATER PLANT OPERATOR TRAINING PROGRAM


Trihalomethanes THMs



Factors influencing THM formation
  • temperature
  • pH
  • precursor concentration (TOC, UV-absorbence)
  • chlorine dose and residual
  • contact time


THM Reduction Strategies
OptionAdvantagesPotential
Disadvantages
Capital
Costs
THM
Levels
Comments
1. Chlorine deferral     
a) post sedimentation
  • simple
  • slime
  • disinfection
  • zebra mussels
  • lowlower
  • little change to current operating procedures will be required
  • chlorine contact tanks may be necessary
  • b)post filtration
  • simple
  • slime / mudballs
  • disinfection contact time
  • zebra mussels
  • low to medlower
  • little change to current operating procedures will be required
  • chlorine contact tanks will be necessary
  • 2. Change disinfectant     
    a) chlorine dioxide
  • simple
  • health effects of DBPs may be greater than for THMs
  • zebra mussels
  • lowvery low
  • disinfection by-products may be subject to future regulations
  • the effect on zebra mussels is not yet clear
  • potential foul odour
  • b)ozone 
  • health effects of DBPs may be greater than for THMs
  • complex technology
  • high operating costs
  • zebra mussels
  • highvery low
  • disinfection by-products may be subject to future regulations
  • the feasibility for zebra mussel control is not clear at this time
  • c)pre-chlorination
  • simple
  • disinfection contact time
  • zebra mussels
  • disinfection compromised?
  • medlow
  • large chlorine contact tanks will be necessary
  • d)post-chlorination
  • simple
  • more persistent residual in the distribution system
  • post-chlorine dosage may be lower at present
  • possible nitrification in the distribution system
  • lowlower 
    3. Powdered activated carbon
  • simple
  • also removes other organics
  • generates large amount of waste (dosage dependent)
  • operating costs may be high
  • lowlow
  • carbon is added during flocculation on an "as needed basis" and is used only once
  • will prompt immediate need for waste treatment facilities
  • 4. Granular activated carbon     
    a)biologically active
  • SIMPLE
  • ALSO REMOVES OTHER ORGANICS
  • OPERATING COSTS MAY BE HIGH
  • MEDlow
  • carbon will be replaced / regenerated periodically
  • not biologically active
  • simple
  • also removes other organics
  • operating costs may be high
  • medlow
  • carbon will be replaced / regenerated periodically (more often than in 4a)
  • 5. Aeration post-filtration
  • also removes other visible organics
  • complexhighlow
  • moves an undesirable substance from water to air